Eric Shaqfeh

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Eric Shaqfeh is the Lester Levi Carter Professor as well as a professor of chemical engineering and mechanical engineering at Stanford. He became chair of the chemical engineering department in 2011. His awards include the APS Francois N. Frenkiel Award, the NSF Presidential Young Investigator Award, the David and Lucile Packard Fellowship in Science and Engineering, the Camile and Henry Dreyfus Teacher-Scholar Award, and the Bingham medal from the Society of Rheology.  He is a Fellow of the American Physical Society, and served as an Associate Editor of Physics of Fluids since 2006. He has authored or co-authored over 170 publications in the general area of complex fluids and non-Newtonian fluid mechanics. He received his BSE in Chemical Engineering from Princeton University and his MS and PhD degrees in Chemical Engineering from Stanford University. 

My research program includes the study of different areas associated with transport in complex fluids including: a) the occurrence of purely elastic instabilities in polymer flows, b) the micro-dynamics of polymer molecules, including DNA, in nonequilibrium transport, c) the flow behavior of fiber suspensions, d) the general microfluidic flow behavior of complex fluids and, most recently, e) the stability of compressible boundary layer flows. Our group's approach in these areas includes developing large scale simulations (including both Brownian dynamics and continuum simulation) of poorly understood phenomena and then couple these to detailed experiments to elucidate the important physics in a variety of processes.

To view Shaqfeh's full Research Statement and Ph.D. Students list, see his department page.

Last modified Fri, 18 Jan, 2013 at 10:56

Title Author(s) Journal Date
Ergodicity-Breaking and Conformational Hysteresis in Polymer Dynamics Near a Surface Stagnation Point V.A. Beck; E.S.G. Shaqfeh; J. Chem. Phys. 03-2008
The Coil-Stretch Transition after More than Thirty Years 03-2008
Progress and Prospects in Understanding Single Molecule Polymer Dynamics in Flow 10-2007
Unique Phenomena in the Microfluidic Flows of Polymers or Particles 10-2007
Issues in the Microfluidic Flows of Complex Fluids 09-2007
Dynamics of DNA tumbling in shear to rotational mixed flows: Pathways and periods J.S. Lee; E.S.G. Shaqfeh; S.J. Muller; Phys. Rev. E 01-2007
Ergodicity-Breaking and the Unravelling Dynamics of a Polymer in Linear and NonLinear Extensional Flows V.A. Beck; E.S.G. Shaqfeh; J. Rheol. 01-2007
The Individualistic Dynamics of Entangled DNA in Solution R. Teixeira; A.K. Dambal; D.H. Richter; E.S.G. Shaqfeh; S. Chu; Macromolecules 01-2007
Dynamics of DNA polymers in post arrays: Comparison of single molecule experiments and simulations N.P. Teclemariam; V.A. Beck; E.S.G. Shaqfeh; S.J. Muller; Macromolecules 01-2007
The Dynamics of the Coil-Stretch Transition for Long, Flexible Polymers in Planar Mixed Flows B. Hoffman; E.S.G. Shaqfeh; J. Rheology 01-2007

1991-96 David and Lucile Packard Fellow in Science and Engineering 1998 Curtis W. McGraw Research Award from the American Society of Engineering Education 2000 Fellow of the American Physical Society September 2001 Van Ness Lectureship, Department of Chemical Engineering, Rensselaer Polytechnic Institute 2003 Stanley Corrsin Lectureship, Department of Chemical and Biomolecular Engineering, The Johns Hopkins University 2004 Hougen Professor, Department of Chemical Engineering, University of Wisconsin 2006-present Associate Editor of Physics of Fluids, Bingham Medal 2011, Society of Rheology

Dynamics of Suspensions of Anisotropic & Deformable Particles in Sedimentation

The Dynamics of Suspensions of Anisotropic and Deformable Particles in Sedimentation
(Collaboration with Eric Darve and Juan Santiago, Mechanical Engineering);

For more than a decade, our group has examined the dynamics of nonBrownian fiber suspensions noting that the flow dynamics under all types of situations is qualitatively different than that found in suspensions of spheres. The simplest difference comes in the effect of hydrodynamic interactions where a given high aspect ratio fiber can interact with many of its neighbors before it ever interacts with its opposite end (!). Such semi-dilute fiber suspensions have properties which are dramatically different than their Newtonian suspending fluid even at remarkably small volume fraction. A second profound effect in fiber suspensions is associated with the mobility or drag coffiecient depending on orientation for fibers, and thus in sedimentation, fibers move rapidly in directions perpendicular as well as parallel to gravity. The consequence of this for a sedimenting suspension of fibers is that the suspension does not remain homogeneous but spontaneously forms "clumps" or "packets" which settle more quickly than an isolated fiber. We have discovered by simulation and theory, as well as by detailed experiment, that there is a region of particle concentration where the average sediment velocity is actually larger than the isolated particle rate. This finding brings new meaning to the phrase "hindered settling function"! This sedimentation velocity in suspension is therefore critically dependent on the "clumps" which form in the suspension. In new work, we have shown that this instability is generic to all separation processes involving deformable and orientable particles. In microfluidic applications, the induced electro-osmotic flows around the orientable particles creates new effects on this instability that we are examining in the context of simulating the operation of

Polymer Conformational Hysteresis in Mixed Flows

Polymer Conformational Hysteresis in Mixed Flows

We aim to study the non equilibrium behavior of polymer molecules in flows of dilute solution. It has been shown that polymers undergo a coil-to-stretch transition (unraveling) in extensional flow. In addition, this transition exhibits a hysteresis; that is, both the coiled state and the extended state can co-exist at the same flow strength, depending on initial conditions. This transition can be analyzed as a pseudo first order phase transition by calculating an effective energy barrier between the two states, and the rate of state hopping can be obtained. We wish to develop a rate theory for the coil to stretch transition in more general mixed (extensional + vortical) flows and analyze the effective conformational energy barrier as a function of flow mixedness. To accomplish this task, we are performing Brownian dynamics computer simulations coupled with single molecule fluorescence experiments using DNA as a model polymer. These BD simulations are able to capture essential polymer dynamics, including hydrodynamic interactions and the coil-to-stretch hysteresis.